Transition-Metal-Catalyzed Annulative Coupling Cascade for the Synthesis of 3-Methyleneisoindolin-1-ones

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초록

This short review describes the recent progress made on transition-metal-catalyzed annulative couplings for the synthesis of 3-methyleneisoindolin-1-ones, which are useful intermediates for the synthesis of numerous alkaloids and can be often found in a wide range of natural products and pharmaceuticals. In particular, new one-pot multiple C-C/C-N bond-forming processes for the construction of the 5-methylenepyrrol-2-one nucleus of such compounds are summarized.

키워드

N-heterocyclesisoindolinonestransition-metal catalysisC-H functionalizationcascade reactionscyclizationscoupling reactionsC-H ACTIVATIONNITROGEN-CONTAINING HETEROCYCLESPOSSESSING INHIBITORY-ACTIVITYMIYAURA DOMINO REACTIONS1ST TOTAL-SYNTHESISONE-POT SYNTHESISN BOND FORMATIONSTEREOSELECTIVE-SYNTHESISEFFICIENT SYNTHESISHIGHLY REGIO
제목
Transition-Metal-Catalyzed Annulative Coupling Cascade for the Synthesis of 3-Methyleneisoindolin-1-ones
저자
Youn, So Won
DOI
10.1055/s-0039-1690046
발행일
2020-03
유형
Review
저널명
Synthesis
52
6
페이지
807 ~ 818